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Hoffman Apparatus on the Go....

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Hoffman apparatus

What are we doing to help kids achieve?

     We reached the topic of bonding and I wanted to do some demonstrations and/or experiments to get kids thinking. Thanks to my modeling friend and colleague Mary Palmer I decided to steal an idea from the American Modeling Teacher's Association. Here was the plan: The idea was to start with electricity.  Students first do an experiment with static electricity. They can take some small pieces of paper and rub a plastic ruler against their head or sweater. The paper then "jumps" to the ruler when it is close. Have students come up with a model or explanation with few words as possible. This serves two purposes...first, there is some formative assessment. It helps me to see where students are at in their understanding of charges and electricity. Second, it starts to plant the idea that "stickiness" and electricity are somehow connected.

     Next, I wanted to have the students work with a Hoffman apparatus. There are many places online to build a DIY Hoffman apparatus. The ACS offers an electrolysis of water lesson that includes a hand made Hoffman apparatus as part of a unit on energy that I used as a resource. For a power source I stopped by our local internet provider. They often get in old broken modems and throw them away. They are more than happy to provide me with the 9 volt power source. This saves me from having to use 9 volt batteries that get expensive. Next, I stopped by the local hobby shop to explore the remote control plane section. They sell these very thin and strong graphite/carbon rods used in building the wings of these planes. Cutting these up into 1 inch pieces makes nice electrodes that do not react with anything over time. I then strip some of the insulation off of the wires and purchase some heat shrink wrap at the same hobby store. I simply twist the bare wire on the carbon electrode add the shrink wrap with a little heat from a hair dryer and the wires are now connected to the electrodes. Next, it is time to "dumpster dive" into my recyclying bin at school and get some water bottles. I cut them in half. I then take a hot nail and poke a hole in the lid to fit the electrodes and add hot glue to helps stop leaks. The lid is srewed on and then carefully placed in a ring stand. The other half is used as a cheap beaker. Students are provided with .1 M sodium sulfate solution, told to pour it in the inverted top with the electrodes and plug it in.

  Bubbles started and so did the questions....Are there the same amount of bubbles on both sides? What are the bubbles? How do we capture them? Some students thought they were air or electricity. Mike Geyer came up with great teaching strategy...make a model of everything in the beaker. I convinced the students that the sodium sulfate was just a catalyst so let's look at the other items...water. We made models of water. One class then started asking...what happens if we took the models apart? Sure enough....we got a 2 to 1 ratio of hydrogen to oxygen...more bubbles on one side than the other. One group got some cheap plastic pipets and without me telling them started to capture the bubbles. When we placed a lit match to the one pipet...sure enough...there was a small popping sound indicating hydrogen.

     It did not work this well in every class but at least it was a start and provides ideas for the next time around. Many people have had issues with getting a 2:1 ratio of gases using sodium sulfate solution and have suggested that 1 M NaOH works well. I recently read this on the Modeling listserve and have not tried the different solution yet....I would like to suggest this might be a great experiment for students to tackle......Let me know what you think...

For more detailed information on building your own Hoffman apparatus, I suggest you follow the link to the Foundations of Energy website for lessons created by high school teachers and ACS. The resources there are available partly because of a grant from BP.


Building Models of Isomers

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organic model kit

I have been looking at model building labs in some of my previous posts and would like to continue with that theme. In my last post I talked about an activity where students try to recognize functional groups by examining previously built molecules. This time I want to focus on an activity where they build multiple models to try and identify isomers.

My basic approach to these activities is always the same. I want students to be building models and have myself walking around from station to station to critique their models and make them keep building until they get it correct. The paper that accompanies this assignment is very easy for me to grade. I rubber stamp each structure once they get it right. They must have all the models of a specific compound in front of them to get the credit for building. This is great because it means that they see both (or more) structures at the same time.

I am sure that this is not a new activity but I have taken it and tailored it to my style of teaching. I love to be able to walk from station to station for the whole period and have multiple interactions with each student. In fact there is no way a student can get through the activity and not have a conversation with me. I have tried several variations of grading this. One is that you can have one paper per two students or one paper per person. I have also considered and once tried a paper for a group of four kids. This speeds things up nicely when it comes to checking papers! Usually I pick a point value for each stamp earned and just count up the number of stamps at the end of the period. On some occasions I have had strong classes where I knew at the end of the period every kid had a perfect score and that allowed me to not collect papers, but to just give everyone present a perfect score.

I think the moral of my story here is to stay away from the canned lessons that you see from publishers. Look at a lesson and tailor it to your needs, your equipment, and your class time. What works for one teacher may not work for another.

Concepts: 

isomers, positional isomers, structural isomers

Time required: 

one 50 minute class

Materials: 

Enough organic molecule sets for each group to build all of the isomers.The molecular model kits I use are from Carolina: Advanced Level Chemistry Set Article Ref: MMS-002 - 64. 

Background: 

The first molecules we look at are C2H4Cl2. This is a simple positional isomer but since it is the first one we build, many of my students think simply twisting the molecule makes an isomer. It provides a great opportunity to show that to be an isomer you cannot have two molecules that can be superimposed in any way. Once a student gets this concept the rest of the activity goes much faster.

The second species we talk about is C4H10. I am sure many of you have had students take this straight chain and turn it into a U and a Zig Zag and think that they were different. This molecule shows structural isomers nicely by making the students figure out that butane and 2 methyl propane have the same molecular formula but different structures.

The third scenario is a variation of C4H10. I tell my students to keep those models and use them as the basis for their next answer. The new molecule is C4H9OH. There are four distinct isomers of this alcohol and if the groups of two students work with another group of two they have the ability to show all four at the same time. This is a very challenging set for most students but I am always impressed that some groups get it immediately.

My next scenario is C4H6. There are two isomers possible by moving the triple bond. Students get this one fast. I tell them in advance that it must have a triple bond. One time I didn’t and that made for lots of confusion.

C4H8 is the next molecule. This contains a double bond and brings in the idea of cis trans structures in addition to the movable position of the double bond. This is without a doubt the most difficult isomer for my students to get. It takes a considerable amount of time for them and I love it because it pushes them into really applying themselves.

The last scenario is hexane. I actually do not have students build these, they only have to draw them. I like this for several reasons. One is that if a student is not finished by the end of the period they can do it at home. If they are done with their model building it is a nice and more involved question that produces five isomers and takes some good thought. I do allow students who are finished to walk around the room also to interact with other groups. I am very fond of the discussions I hear come out of activities like this.

Procedure: 

Using the assignment page, build the assigned molecules using the molecular model kits. You are told how many isomers of each you need to build. Get them approved and stamped by the instructor. Once you have the correct model, draw a simple diagram of each structure and write name the compound next to it. 

Preparation: 

Aquire model kits

Attribution: 

I created this activity for use with my students at Francisco Bravo Medical Magnet High School, Los Angeles, California.

Exciting Summer Research Opportunity for Teachers in Indiana and Alabama

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RET PD

The RET Site is a unique professional development opportunity for STEM teachers from Indiana and Alabama over six weeks in the summer of 2017. Teachers will conduct research and participate in professional development. All participants will be provided funding and support to implement new, standards-based curricula into their science courses at their respective high schools. See the RET announcement.

Time: 
Monday, June 5, 2017 - 00:00 to Friday, July 14, 2017 - 00:00

Introduction to the Claim, Evidence, Reasoning (CER) Framework

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AMTA

Free webinar for all AMTA members!

This webinar will introduce the Claim, Evidence, Reasoning (CER) Framework, implementation strategies, and how it helps create a classroom culture that more accurately reflects the ways progress in scientific knowledge and communication take place in the real world.  An interest in this framework stems from the idea that a hallmark trait of science is the natural filter it places on our understanding of the world around us. Though anyone is free to make claims about objective truths, these claims are subject to immense scrutiny of supporting evidence for them and the reasoning used to account for why such evidence is appropriate as well as how it all fits into our understanding of the natural world.  Even with this framework playing a large role in the foundation for which scientific knowledge is built and communicated, it rarely seems to effectively make its way into science education. 

This webinar will be hosted by Ben Meacham, a Chemistry teacher at Prior Lake High School in Minnesota. As an educator, Ben has taught Physics, Chemistry, Physical Science, Astronomy, and Geometry. He became affiliated with Modeling Instruction the summer before his first year of teaching and has implemented both the Chemistry and Physics Modeling Instruction curricula. You can follow him on Twitter @meachteach or visit his blog for more information.

Event Type: 
Time: 
Wednesday, February 22, 2017 -
19:00 to 20:30

Investigating the Effect of Concentration on Reaction Time

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Concentration vs Rate of Reaction

Whether you are introducing collision theory or something more demanding like reaction order, the reaction between sodium thiosulfate—Na2S2O3 and hydrochloric acid can provide a consistent, accurate, and engaging opportunity for investigating these topics.

A few weeks ago, I was looking for a new reaction that could be used to investigate how concentration affects reaction time. In the past, I had always used traditional reactions such as magnesium and hydrochloric acid or Alka-Seltzer and hydrochloric acid. Though both served their purpose, there would always be groups that didn’t quite get data that was consistent with what I knew the relationship to be. In most cases, this was due to ambiguous and inconsistent timing methods or simply a matter of experimental error like not ensuring the magnesium stayed in the acid without floating to the top. I wanted a reaction that would be more likely to produce consistent results from group to group, easy to execute, and was a bit more exciting than waiting for magnesium or Alka-Seltzer to disappear.

Eventually, I came across a Flinn1 experiment which focused on the reaction between sodium thiosulfate and hydrochloric acid.

Na2S2O3 (aq) + HCl (aq) à 2NaCl (aq) + S (s) + H2O (l) + SO2 (g)

What I liked most about this reaction was the easy and consistent timing mechanism it provided my students with, which could eliminate the ambiguity and differences in timing approaches that lab groups had used in the past.

Here’s how: As the reaction proceeds, one of the products is sulfur. As more sulfur gets produced, the solution becomes more and more cloudy until eventually the solution is opaque. Because of this, the moment that you can no longer see through the solution can be used as a consistent way to stop time. When I asked my students how we would all consistently decide on when the solution is opaque, many of them suggested to place some sort of object on the other side of the beaker so that we would all stop the timer when the object was no longer visible. This naturally progressed to the idea of drawing something on the beaker itself (an X on the bottom in this case) and applying the same reasoning.


This reaction and the implementation of this natural clock can be seen below in a Flinn video2.

Even though it is just a matter of changing from visible to opaque, I noticed that the anticipation of waiting for that X to disappear had nearly all my students hovering over their beakers anxiously waiting to stop their timer. It even got to a point where different groups started to use their phones to make time lapse videos of their reaction beakers. You can see one below. As a teacher, it was fun to watch their level of excitement over something so seemingly simple.

Though I used this experiment to primarily investigate collision theory and different factors that affect the time it takes for a reaction to complete, it could easily be used to determine something more complex like reaction order (see the entire Flinn video from which the above clip is taken).

I also found this lab to serve as a great opportunity for my students to play a larger role in the creation of the experimental setup since there wasn’t much complexity to it. I facilitated the design of the experiment by asking my students a series of questions that were meant to feel like it was a genuine conversation happening between scientists interested in answering a question. The PowerPoint that I used to help facilitate this discussion can be found as Supporting Information at the bottom of this post if you are logged in to ChemEd X, but the general theme followed these questions:

  • What is our independent variable? How should we go about changing this?
  • Should the total volume of each beaker be the same or different? Why?
  • What is our dependent variable?
  • Are there any variables that we should control?
  • How should we go about timing our reaction?
  • How should we record and organize our data?
  • How are we going to figure out our concentrations in terms of Molarity?
  • How should we record and organize our data?
  • What are we going to do with our data once we have it? Graph it?

I don’t include students in things like this often enough and it’s important that I continue to remind myself the beneficial experience this can provide for students to get a more accurate understanding of how science operates.

However you decide to do it, the general approach to this experiment goes something like this:

1) Using a Sharpie, draw a black X on the bottom (outside) of each beaker.

2) A stock solution of 0.15 M Na2S2O3 is used to make 5 different concentrations using different amounts of distilled water, though our tap water worked just fine too. The total volume of each solution should be the same in each beaker.

3) Add 5 mL of 2 M HCl to your first beaker to start the reaction. You can give it an initial stir to uniformly distribute the HCl. The timer starts after this initial swirl.

4) While looking down at the beaker, stop the timer the moment you see the X completely disappear from sight.

5) Do this for all your samples and start analyzing your data

After everyone had finished the experiment and analyzed their results, I was thrilled to see that the data from each group produced a graph that displayed the relationship I was looking for. Not a single group had one weird outlier or a graph with seemingly random points all over the place! Some of the groups even paid close enough attention to the fact that each beaker had different levels of “opaqueness” to them. This provided a great opportunity to talk about the benefits of qualitative evidence as well. I attribute these consistent results to two primary things:

1) Consistent timing mechanism that each group can easily reproduce

2) It is almost impossible to mess up this reaction—you’re just pouring HCl into your Na2S2O3 solution. Minimizing chances for experimental error was huge.


Though I don’t always shoot for consistent data between groups when we do a lab, I knew that the arguments would vary between groups when trying to explain why their experiment displayed the relationship it did. It is the arguments I am most interested in developing after students complete their data analysis.

Students were tasked with developing their initial argument using a Claim, Evidence, Reasoning (CER) framework. Though most boards had similar claims, they often differed in what evidence they chose to present. They all had access to the same evidence and yet different groups intentionally left out certain pieces of evidence—why? Where their boards differed the most was in their reasoning, which is meant to have them justify why their evidence makes sense based on known scientific principles. I should mention that the students had not been presented anything about collision theory before this lab and yet many of them were able to come up with a valid particle-based explanation while others either circled around ambiguity, lacked detail, or simply displayed some form of misconception. The important part of this was that they tried their best, based on the models they had running around in their heads, to explain the phenomenon and knew that it was up to the scientific community (our class) to act as a filter for sorting out valid explanations from ones that either lacked detail or could not quite account for the evidence. This is the process I love doing the most.

The lab itself took about 30 mins to do but because I involved them in the experimental setup and dedicated time to construct arguments that were presented, debated, and refined, the entire process took 3 periods (1 hr each).

I want to thank Flinn for inspiring the idea for the experiment in the first place and NSTA’s book Argument-Driven Inquiry in Chemistry3 for providing the framework we used to set up and make sense of the investigation.

Resources

1Rate of Reaction of Sodium Thiosulfate and Hydrochloric Acid. N.p.: Flinn Scientific, n.d. Pdf. https://www.flinnsci.com/globalassets/flinn-scientific/all-free-pdfs/dc91860.pdf

2 "Rate of Reaction of Sodium Thiosulfate and Hydrochloric Acid..."20 Dec. 2012,  https://www.youtube.com/watch?v=r4IZDPpN-bk. Accessed 17 Jan. 2017.

3"NSTA Science Store: Argument-Driven Inquiry in Chemistry: Lab ...." 1 Oct. 2014, https://www.nsta.org/store/product_detail.aspx?id=10.2505/9781938946226. Accessed 17 Jan. 2017.

    Mid-Year Reflections

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    concept map

    It’s the end of one semester and the beginning of another. Final exam week. For the first time in my teaching career, I had my grades caught up and posted prior to the beginning of final exams. This gave me time to reflect and plan ahead.

    Here are some highlights of the fall semester:

    • More frequent utilization of Google Classroom for warm-ups, lab reports, and blended lessons.

    • The introduction of Gizmos activities.

    • Updated Nuclear Chemistry unit with NGSS focus.

    • Updated Chemical Reactions unit with NGSS focus and Gizmos lessons.

    • Updated Physical Properties unit with Gizmos and Target Inquiry activities.

    • Abstract accepted for 2017 MACUL Conference in Detroit, MI.

    • Mentored a pre-intern from Western Michigan University.

    • Concept Mapping for final exam review.

    Projections for the spring semester:

    • Update my Google Site to be more user-friendly.

    • Mentor another pre-intern from Western Michigan University.

    • Continue frequent use of Google Classroom including daily agenda that was introduced in December. As part of my district’s recently adopted 5D+ evaluation model, I set out to have a Google Doc displayed in each class that displayed the Learning Target(s), Performance Task(s), and Success Criteria, in addition to the agenda and relevant warm-ups.

    • More warm-ups!

    • Continue blended lessons where appropriate.

    Questions to figure out before next semester:

    • During the Relative Reactivities of Metals lab in our Chemical Reactions unit in December, students mixed Zn metal with aqueous Zn(NO3)2. Several students observed what appeared to be a black precipitate forming in the aqueous layer. I performed the experiment and observed a similar result. My hypothesis is that the Zn metal strip had not been polished with steel wool to remove the oxidized layer on the surface. It is possible that this layer was being “washed” off the metal’s surface and presented itself as a black precipitate. I will revisit this next semester. What are your thoughts?

    AACT Webinar Series: A Visual and Intuitive Approach to Stoichiometry

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    This webinar will discuss how to approach teaching stoichiometry problems using a table set-up (commonly referred to as Before, Change, After tables) to make the process visually appealing and more intuitive for students. The process emphasizes proportional reasoning and explicitly connects the calculations to the particulate nature of matter.

    Connections to equilibrium calculations will also be discussed to show how this method can easily be integrated in to your curriculum and benefit your students in more than one area.

    Webinar hosted by Kaleb Underwood

    Event Type: 
    Time: 
    Tuesday, February 7, 2017 -
    19:00 to 20:00

    AMTA Webinar Series: Engineering in the Modeling Classroom

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    engineering

    Free Webinar for all AMTA members!

    The NGSS calls for the use of the engineering design process in science classrooms K12.  Let’s discuss what this means for the modeling classroom.   Bring your ideas about how and when to integrate the engineering design process and engineering projects into your classroom.  

    This session will be hosted by Kathy Malone and Anita Schuchardt. 

    Event Type: 
    Time: 
    Tuesday, February 7, 2017 -
    19:00 to 20:30

    The Case of the Barking Dog

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    hydrogen test

    To grasp the concept of oxidation and reduction reactions, I have my high school students write half reactions to show the loss and gain of electrons by the substances being oxidized and reduced. To help with this concept, I developed a quick lab activity involving the reaction between magnesium metal and dilute hydrochloric acid, which in turn led to the students collecting the hydrogen gas and then testing for its presence. The lab was a success as I watched startled students produce the so-called barking dog sound as they combusted the hydrogen gas in their inverted test tubes.

     However, When it came time to write the half reactions, particularly for the combustion of the hydrogen gas with the oxygen gas to produce water, my students were confused regarding when to write subscripts vs coefficients. 

                Balanced equation:   2H2  +  O2à 2H2O

                Student example:

                Oxidation half reaction: 2 H20  à2H2+ + 4e- incorrect

                compared to

                Oxidation half reaction: 2H20  à4H+ + 4e-   correct

    The same was true with the original reaction showing the H+ of the hydrochloric acid vs the H2 of the hydrogen gas produced. 

    This time the students were not copying the equation but just did not understand when to use a coefficient or a subscript.

                Mg(s)  +  2HCl(aq)  à MgCl2(aq)  +  H2(g)   

                Reduction half reaction: 2H+ +  2eà  H20    correct

                compared to 

                Student example:

                Reduction half reaction: 2H+  + 2eà  2H0  incorrect

    What was happening was my students were copying down exactly what was written in the original equation without thinking about what this looked like on the particulate level. This required me to get a little creative and I had remembered Michelle Okroy’s blog about the program molview. I thought that if the students could build and see the structure of the hydrogen molecule vs the water molecule then they may gain a better understanding of why 4H+ was correct vs the 2H2+ and when to use it. I hoped that by looking at the structure of these two molecules that maybe they would see the difference between the two substances. With a class set of iPads we went to the http://molview.org/ site and began to explore.

    After a quick tutorial, I had my students build hydrogen gas and then build the water molecule and compare them. The program works seamlessly on the iPads and my students loved being creative with it. 

     

    When I questioned my students regarding what was different between the two pictures they responded by saying that in the hydrogen gas picture the two hydrogen atoms were connected to one another while in the water molecule picture they were not.  My students were familiar with hydrogen existing as a diatomic molecule and once we assigned oxidation numbers they recognized hydrogen now as an ion and as H+. We still had a learning curve with MgCl2 in the original equation with some students writing Cl2 but they developed a somewhat rule of how to write them when diatomic vs as when they are shown as an ion.  Luckily, chlorine is a spectator ion in that equation but they applied their rule to the hydrogen and gained success with more practice when asked to write the half reaction on their assessment. If you log in to your ChemEd X account, you can download the student and teacher versions of the activity.

    Concepts: 

    redox

    Time required: 

    50 minutes

    Materials: 

    Per group: two small test tubes, app.10 mL 3.0 M HCl, 1-2 cm Mg ribbon, a wooden splint, matches

    Background: 

    .

    Procedure: 
    1. Obtain two test tubes of similar size and place one test tube in the test tube rack. 


    2. Obtain a small amount of hydrochloric acid in a small beaker 


    3. Fill the test tube with hydrochloric acid so that it is level with the top of the test tube rack. 
(about 10 mL) 


    4. Obtain a small piece of magnesium metal and place it into a dry test tube and hold onto the test tube with a set of test tube clamps. 


    5. Invert the test tube with the Mg overtop of the test tube with the hydrochloric acid so that the Mg falls into the hydrochloric acid. Keep the test top on top of the other test tube in order to capture the hydrogen gas that is being given off. 


    6. Once the reaction stops, quickly have your partner bring a lit wood splint near the opening of the two test tubes (perpendicular) as you slowly slightly tilt the top test tube away from the flame and listen for a reaction to occur. 


    7. Once the reaction is done pour out your remaining hydrochloric acid, clean up, and complete the laboratory questions.

    Questions: 

    Magnesium metal reacts with hydrochloric acid to produce aqueous magnesium chloride and hydrogen gas

    1. Write a balanced equation showing this reaction and include the states of matter.

    2. List the oxidation numbers of each element individually.
 (remember any element in its pure state is assigned an oxidation of zero, even in its molecular form.)

    oxidation numbers

    Mg ___

     

    Hydrochloric acid H ___ Cl ___

    Magnesium chloride Mg ___ Cl ___

    Hydrogen gas
H ___

    3. What substance is being oxidized?

    4. Write the half reaction for the substance being oxidized.

    5. What substance is being reduced?

    6. Write the half reaction for the substance being reduced.

    7. Is there any substance that is a spectator ion? yes or no? If so list

     

    Hydrogen gas reacts with oxygen gas to produce water.

    9. Write a balanced equation showing this reaction.

    10. List the oxidation numbers of each element individually.


    oxidation number

    H ___

    O ___

    H ___ O ___SUBJET: CHEMISTRY B - REDOX MR. RAGAN

    11. What substance is being oxidized?

    12. Write the half reaction for the substance being oxidized.

    13.What substance is being reduced?

    14.Write the half reaction for the substance being reduced.

    15. Is there any substance that is a spectator ion? yes or no? If so list

     

     

    Preparation: 

    lab setup, see attached

    Credits: 
    NA
    Attribution: 

    Thanks to Michelle Okroy for the advice related to using Molview (as mentioned above).

    I created the worksheet for my own students. 

    Chemical Connections to Climate Change

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    carbon dioxide absorbing IR light

    Chemical Connections to Climate Change

    Did you know that climate change can be used as a backdrop to discuss several ideas in chemistry? In this post I’ll describe how several chemical concepts including Beer’s Law, the chemical composition of the atmosphere, combustion chemistry, and solutions can all be used in a discussion of how CO2 keeps our planet warm – and how excess CO2 warms it even more.

    Composition of the atmosphere

    We’ll start by treating our atmosphere as a solution. Several different gases make up our atmosphere (Table 1). Because N2(g) is the compound present in greatest amount in the atmosphere, N2 is the “solvent” in our atmospheric “solution”. The solute present in largest amount is O2 (g), but certainly there are many others.

                                                    Table 1: Gases present in the atmosphere

    Gas

    Name

    Percent by volume

    N2

    nitrogen

    78%

    O2

    oxygen

    21%

    Ar

    argon

    1%

    H2O

    gaseous water

    0 to 4%

    CO2

    carbon dioxide

           0.04% and increasing

    The greenhouse effect

    Some of these solute gases warm our planet by absorbing infrared (IR) light radiation that would otherwise escape into space. Without this warming effect (called the greenhouse effect), the average temperature on Earth would be a chilly 255 K (that’s -18 oC, or the temperature on an extremely cold winter day). Because solute gases in our atmosphere absorb IR light, Earth’s average temperature is 288 K (that’s 15 oC, about the temperature on a slightly cool spring day). Thus Earth is 33 K warmer than what would be expected if there was no atmosphere.1

    While both N2(g) and O2(g) are present in very large amounts in the atmosphere, these gases do not absorb IR light and therefore do not contribute to the greenhouse effect. On the other hand, CO2(g) and H2O(g) do absorb IR light and upon doing so gain energy which is transferred to the rest of the Earth. Even though these gases are present in small amounts, they are very good at absorbing infrared light. Thus, these atmospheric gases are the main contributors to the greenhouse effect. Of the 33 K increase in temperature due to the greenhouse effect, H2O(g) contributes half (16.5 K) and CO2 contributes 20% (6.6 K). Clouds (25%) and other trace gases (5%) make up the remainder.1

    Connection between climate change and Beer’s Law

    Large amounts of CO2(g) are regularly pumped into the atmosphere though various combustion reactions, such as that found during the burning of isooctane (the main component in gasoline):

    2 C8H18 (g) + 25 O2 (g)à 16 CO2 (g) + 18 H2O (g)                  Equation 1

    Climatologists tell us that the resulting increase in atmospheric CO2(g) concentration has the effect of increasing the average temperature on Earth. So let’s ask the question: How much hotter would we expect the average temperature of Earth to rise upon addition of more CO2(g) into the atmosphere?2

    We’ll gain some insight into this question using Beer’s Law, which describes the amount of light absorbed by a compound in a solution:

    A = ebc                       Equation 2

    Where A is the amount of light absorbed, e is the molar absorptivity of the compound (a measure of how well the compound absorbs the light), b is the path length through which the light travels, and c is the concentration of the compound in the solution. In our case, A is the amount of IR light absorbed by CO2(g) in the atmosphere, e is how well CO2(g) absorbs IR light, b would be the thickness of Earth’s atmosphere, and c is the concentration of CO2(g) in the atmosphere.

    Back in 1850, the concentration of CO2(g) in the atmosphere was 285 ppm.3 Today, the concentration of CO2(g) is over 400 ppm.3,4 Let’s use these values and Beer’s Law to estimate the ratio of IR light absorbed by CO2(g) in 1850 (A1850) vs. today (Atoday):

    Based on Beer’s Law, we’d expect CO2(g) to be absorbing about 40% more IR light than it did back in 1850, due to this increase in concentration.

    Let’s find the expected global rise in temperature due to this 40% increase in light absorbed by additional CO2(g). The baseline contribution of CO2(g) to the greenhouse effect is 6.6 K (see above). Let’s set this value equal to the contribution of CO2(g) to the greenhouse effect in 1850. Multiplying this value by 1.4 gives: 6.6 K x 1.4 = 9.2 K. Thus we would predict that the additional CO2 in the atmosphere would increase the contribution of CO2(g) to the greenhouse effect from 6.6 K to 9.2 K. That’s a change of +2.6 K (9.2 K – 6.6 K). Indeed, average global temperatures have risen 1.0 K since 1850.5 Our estimate is in right the ballpark, but well over two times too high. Surely this is because there are many more factors on the global scale that our simple approach has not taken into account. Nevertheless, we can at least gain some insight into how increased CO2(g) concentrations in our atmosphere have caused the average global temperatures to rise…and we can do so using chemistry!

    Do you ever bring up climate change or global warming in your classes? If so, how do you approach the issue? What kinds of chemical concepts do you use to discuss these issues? We would love to hear from you, so be sure to let us know what you think.

    Notes and references:

    1. Schmidt, G.A.; Reto, R.A.; Miller, R. L.; Lacist, A.A. J. Geophys. Res.2010, 115, D20106.
    2. Noticing that combustion reactions release water (Equation 1), it is natural to ask why no one is concerned about increases in global temperature due to increases in atmospheric water vapor. The answer is that water does not “build up” in the atmosphere the way CO2 does (and some other gases do). When “too much” water vapor builds up in the atmosphere, it rains, removing the excess water. 
    3. https://data.giss.nasa.gov/modelforce/ghgases/Fig1A.ext.txt
    4. https://www.co2.earth/daily-co2
    5. http://berkeleyearth.org/land-and-ocean-data/#section-0-0

    ChemEd 2017

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    ChemEd 2017 logo

    CHEM Ed 2017 will be in Brookings, South Dakota on the campus of South Dakota State University from July 23 through 27. Currently the conference program directors are accepting abstract submissions through February 28th within the following strands:  

    Laboratory Instruction

    Technology (online learning or in the classroom)

    Chemistry Demonstrations

    Modeling

    Next Generation Science Strands (NGSS)

    Inquiry Practices (POGIL, PBL, etc)

    Misconceptions in Chemistry

    Blended / Flipped Classroom

    Informal Learning / Learning through Play

    Writing/Reflection/Metacognition and Literacy in Chemistry

    Chemistry in Industry (Food, Forensics, Agricultural, etc).

    Miscellaneous 

    Two plenary speakers at the conference will be Dr. Bassam Shakhashiri from the University of Wisconsin, considered the dean of chemistry demonstrators, and Andy Brunning from theNetherhall School in Cambridge, United Kingdom, creator of the website compoundchem.com.

    Registration will open in March. Consider taking the trip to South Dakota for one of the premier conferences for chemistry teachers. 

    Event Type: 
    Time: 
    Sunday, July 23, 2017 - 12:36 to Thursday, July 27, 2017 - 12:36

    Creating an Organic Chemistry Reaction Pathways Flowchart as a Unit Summary

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    Student generated reaction pathways flowchart

    As a teacher, there are certain things I think I do well, and other areas where I think I can improve. One of these areas is helping students make connections between topics - especially at the end of a unit. Can I get students to see the proverbial "Big Picture"?

    For a recent unit on organic chemistry for my IB students, I tried something new. I gave them a handout with a list of organic compounds (by class/functional group) and a list of mechanisms and reaction types. Their task (in small groups), using either butcher paper or a large whiteboard, was to create a flow chart of reaction pathways. They had to find connections between as many different compounds as possible. I didn't provide much more guidance, but I encouraged the students to discuss their ideas together and consult their notes.

    While they were working, I wandered around the room and commented on any errors or missing pieces I observed. I also started asking questions like, "If I had only a primary alcohol available, what reaction path would it take to make an ester?" (Short answer: Oxidize some of the alcohol under reflux to make the carboxylic acid, then do esterification with the remaining alcohol to form the ester.)

    Below is a picture of one of the whiteboards created by a group (used with their permission).

    Once everybody was done, we continued our work on synthetic routes by going through a few more practice problems. I don't have quantitative data to support my claim here, but I'm convinced that the creation of the flow chart helped the students see connections between the different types of organic compounds and solidified their understanding of the reaction pathways being studied.

    In terms of the compounds and mechanisms chosen, I restricted this list to meet the requirements of the IB syllabus for  both SL and HL organic chemistry. There are clearly many more branches to the reaction pathways that were not included. But it would be easy enough to modify the list to meet the needs of your own curriculum.

    This is certainly an activity I will repeat with future classes. If you are logged in to your ChemEd X account, you can download the handout I provide my students. I would be curious to know how you wrap up your units to help students see connections?

     

    Concepts: 

    Organic chemistry compounds (classes of compounds and functional groups)

    Organic chemistry reaction types and mechanisms

     

    The specifics will depend on your curriculum. The list I used was based on the current IB Syllabus.

    Time required: 

    30-45 minutes

    Materials: 

    Whiteboards or Butcher Paper

    Markers

    Procedure: 

    Students form groups with a large piece of butcher paper or a large whiteboard and some markers.

    They then create a flow chart of reaction pathways using the lists provided on the handout.

    I encourage you to walk around and offer feedback and ask questions along the way to help the students in the process.

    Preparation: 

    I found a quick discussion of the format with an example to be very helpful. The picture below shows the example I used (created using Notability on my iPad, with the .pdf file generated with PowerPoint).

     

     

     

    Attribution: 

    I'm not sure where the idea came from. I recall seeing the "official" reaction flow chart from the IB in their syllabus a few years ago and wanting my students to create the reaction pathways on their own as an activity. 

    Media: 
    AttachmentSize
    Image iconreactionpathways.jpg752.45 KB

    Chemicals Investigations of McCormick's Color From Nature Food Colors. Part 1: Sky Blue

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    Sky Blue dye

    Over the past few years, consumers have been looking for products containing natural rather than synthetic food dyes.1,2 In response to this trend McCormick & Company, Inc. has recently released Color from Nature food colors, which are advertised as “colors made from plants, vegetables, and seeds.”3 A box of Color from Nature contains three packets of powdered dyes: Sky Blue, Berry (red), and Sunflower (yellow). I recently purchased a box from a local store and spent some time investigating and experimenting with these dyes. Wow! These natural food dyes provide avenues for a whole host of interesting, yet easy-to-perform chemistry experiments and demonstrations! I will be sharing many of these explorations with you in a three part series. In this post (Part 1) I’ll be sharing a bit about the chemistry of the Sky Blue food color, along with some experiments and demonstrations that are possible with this food color.

    Spirulina (a blue-green algae) is listed in the ingredients for the Sky Blue dye. Spirulina contain phycocyanin, a protein found in plants. This water-soluble protein does a good job of absorbing wavelengths of light in regions that chlorophyll does not. This helps plants to absorb extra energy from sunlight. Phycocyanin has a beautiful, deep blue color that primarily arises from the pigment phycocyanobilin (Figure 1).

    Figure 1: structure of phycocyanobilin, a pigment in phycocyanin that is responsible for the blue color in spirulina. The pigment is attached to the phycocyanin protein via a cysteine residue.

    As an added bonus, phycocyanobilin displays an intense red fluorescence that can be excited with a flashlight and easily be observed under room lights! Check out some fluorescence experiments you can do with Sky Blue dye in the video below:

    The phycocyanobilin moiety is attached to the phycocyanin protein through a cysteine amino acid. As you can see in the video above, metal ions bind to the phycocyanobilin moiety (Figure 2), and this quenches the fluorescence of the protein.4 I observed this to work using both Ag+ and Cu2+ ions (see video above for tests using Cu2+).

    Figure 2: Possible interaction between Cu2+ and phycocyanobilin attached to protein

    What is interesting about this protein is that when it is denatured, the blue color diminishes and in some cases completely disappears. Likewise, the ability of the protein to fluorescence also decreases when it is denatured. Thus, the use of McCormick’s Sky Blue food colorant provides simple ways to demonstrate protein denaturation that involve a drastic color change from blue to colorless! You can see some of explorations of denaturing phycocyanin in the video below.

    If equipment is available to do so, it is very easy to do some simple spectroscopic experiments with Sky Blue dye. The absorption spectrum of Sky Blue dye dissolved in water is displayed in Figure 3. Consistent with the blue color of the solution, the absorption spectrum peaks in the orange region. The spectrum observed is consistent with previously reported absorption spectrum of phycocyanin in the dye.5 Thus, it is likely that this protein is responsible for the blue color observed in Sky Blue dye. 

    Figure 3: Absorption spectrum of McCormick Sky Blue dye dissolved in water.

    By shining a violet laser pointer at a solution of Sky Blue dye, I was able to acquire the emission spectrum of the dye (Figure 4). The spectrum is clearly consistent with the red color of fluorescence observed. Once again, the structure of the emission spectrum was consistent with previously reported fluorescence spectra of phycocyanin,6 further confirming the presence of this protein in Sky Blue dye.

    Figure 4: Emission spectrum of Sky Blue dye in water excited with a laser pointer (405 nm). 

    As you can see, there are a remarkable number of simple experiments that can be done with the Sky Blue dye found in McCormick’s Color Nature food colors. Be sure to comment if you try out any of these experiments - or invent any of your own to do - with this fascinating dye. In about a month, be looking for part 2 of this series in which the chemistry of the Berry dye will be explored.

    Happy experimenting!

    1. http://cen.acs.org/articles/92/i6/New-Naturals.html

    2. http://cen.acs.org/articles/92/i6/Choices-Natural-Colors.html

    3. http://ir.mccormick.com/phoenix.zhtml?c=65454&p=RssLanding&cat=news&id=2179623 

    4. Gelagutashvili, E.; American Journal of Biomedical and Life Sciences2013; 1, 12-16.

    5. Taylor, A. T. S.; Feller, S. E. J. Chem. Educ.2002, 79, 1467 – 1470.

    6. Suresh, M.; Mishra, S. K.; Mishra, S.; Das, A. Chem. Commun., 2009, 2496–2498

    Ionic Covalent Compounds and Card Sorts

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    Ionic Covalent Card sort

    What are we doing to help kids achieve?

         Card sorts are a great way to achieve a number of classroom objectives. They can be used as a review activity or they can be done during the middle of a lesson as a type of formative assessment. Sorts can encourage students to work with other students or can even be used as a type of exit ticket. I decided to use the strategy about two thirds of the way through a unit on covalent and ionic compounds and lewis structures. I knew there were items we did not cover in the sort but I was curious to see how they would approach these unknown topics. Typically, the sort involve words, diagrams, pictures, properties and phrases on a topic that are easy to put in a document, print, cut up and put in envelopes for groups. Students are instructed to place them in the column "Ionic", "Covalent", or "Both". I decided to try something different. I gave the students about 15 minutes and then told them to make a fourth group with an asteric that was "I don't know".  

         There were six groups and I was able to have discussions with most of the groups that I wish could have lasted longer. The sort provided me with a chance to help clear up some minor misconceptions. More important was the asterick, "I don't know" group. It clearly provided me with topics for future lesson plans. It also was helpful to see that many groups had the same questions. If I could do it again I would have used it at the beginning of the lesson and then at the end.  I also would have had students use their cell phones to take pictures of the "before" and "after" and then discuss the differences (maybe next year.....).

         Assessments, especially formative assessments, do not always have to be electronic or recorded. Some of the best often are not. The bad news about these assessments is that as a teacher I have to go where the students misunderstandings and questions lead us as a class. This often requires a"Plan B" and is sometimes difficult for me, who, as a person and a teacher, is under the illusion that sometimes I am in control of some things. It leads to a "messy" place...but this is where the challenges and fun often get started.

         Have you ever had to take a "U-turn" in your teaching....or had to go to a "Plan B"? What was that like? Would you do it again? Do you have a great formative assessment you would like to share? Let's start a convesation...

    JCE Pick: Improving Student Results in the Crystal Violet Chemical Kinetics Experiment

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    Every year, I have asked my AP students to determine the reaction order of both crystal violet (CrV) and sodium hydroxide (NaOH) using spectrometers. The lab I gave them is a modification of the kinetics lab from Pasco’s Advanced Chemistry Through Inquiry (I wrote about this manual here) and Flinn’s classic write-up. My students found the reaction order of crystal violet to be 0,1, and 2. They found the same with sodium hydroxide. Then I have had to tell them that the reaction order of each is actually 1. Explaining the error analysis is difficult for my students and it has been difficult for me to grade. Have you been there, too?

     


    I recently stumbled upon this article and it is a super handy resource for kinetics labs (and a nice review of Analytical courses from my college days).

    A few potential culprits:

    1. Spectrometer Limitations - deemed to have the most significant effect on data - Remember that time in Analytical Chemistry when you discussed target absorbances to prevent deviations from the linearity we see in Beer’s Law? Right. Absorbances of CrV should be between about 0.1 to 0.7. So, suppose you are like me and don’t make solutions particularly carefully because you don’t care what the numbers are. You just care what your students can do with the numbers. This is the “fake it” method of making the CrV solution- add a drop or two of concentrated CrV and call it a day. What I should do as an addendum to the “fake it” method of solution preparation is to double check the absorbance and adjust accordingly. (I now have to apologize for "faking it" to my past students.)

    2. Signal Processing - When does a student know when to stop collecting data? The authors tested a few different scenarios - but stopping at a common absorbance seems to be the best option. Additionally, authors discuss the benefits of LoggerPro vs Excel… but I have unfair bias towards Excel so I choose to ignore it (my husband is an engineer...enough said).

    3. Interference from Particulates - Have you ever noticed (and ignored) that the final solution is a bit “milky-white” and not perfectly clear? While not deemed to be a major culprit by the authors, it might be a “tangible” source of error to discuss with your students.

     

    The authors conclude with some practical guidelines aligned with the aforementioned culprits. All in all, in my completely biased opinion, this article satiates my desire for an efficient, practical, immediately-applicable article. It’s worth a full read - and if your students are ready, it might be valuable for them to read it too.

     

    Thank you to the authors for publishing this - I hope I represented it well. I hope to see more like this in the future!

    PS - If you don’t have access to colorimeters/spectrometers, check out Tom’s post on how to use smartphones as an absorption spectrophotometer.

    Citation: 

     

    Kazmierczak, N.; Vander Griend, D. A. J. Chem. Educ.2017, 94 (1), 61–66. DOI: 10.1021/acs.jchemed.6b00408

    Year: 
    2017
    issue: 
    1
    Page: 
    61
    Chemistry Domain: 

    Flinn Scientific and Beyond Benign Launch Partnership to Deliver Green Chemistry Learning Solutions to Science Educators

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    Partnership Advances Sustainable Science and Green Chemistry Education K-20 

    to Build a 21st Century Skilled WorkforceCapable of Green Technological Innovation 

    Wilmington, MA—Beyond Benign, a national nonprofit, established in 2007 to equip educators, scientists, and citizens with the tools to teach and practice green chemistry to achieve a sustainable society, just announced a strategic partnership with Flinn Scientific.

    Beyond Benign and Flinn Scientific will co-develop products for use in high school chemistry and introductory college chemistry courses that provide science educators with green chemistry learning solutions.

    Known as the science of creating safe, energy efficient and less toxic processes and products, green chemistry supports an important sustainability narrative that society may incorporate into action to benefit human health and the environment. With the global market for green chemistry projected in a Pike Research study to grow from 11 billion in 2015 to nearly 100 billion by 2020, there is a pressing need to advance this work as quickly as possible.

    “Flinn Scientific is a well-respected and service driven company with a deep history in science education. Through this partnership, we anticipate bringing much needed green chemistry learning resources to an expansive audience of science educators that we may not otherwise reach. This is important because our educational pipelines are mostly void of sustainable science curriculum applied to chemistry and materials science. Green chemistry provides the opportunity to green the student pipeline from K through 20, giving students a grounding in the principles of and applications of chemistry for solving real-world problems. We couldn’t be happier about the collaboration.” said Amy Cannon, Executive Director Beyond Benign.

    “Flinn is also extremely excited about our partnership with Beyond Benign. They are experts in the fields of green chemistry and green chemistry education. We look forward to working with Beyond Benign to provide high quality, engaging lab activities to support these growing areas of science education.” said Mike Lavelle, Chief Executive Officer, Flinn Scientific.

    The first four labs developed by Beyond Benign and Flinn include:

    • Design and Function-Blackberry Solar Cell: Use fruit to build a dye-sensitized solar cell (DSC) and measure its electrical characteristics. This experiment, developed will bring chemistry from the abstract into students' everyday world. Concepts: solar cells, alternative energy, electrochemistry and nanotechnology.
    • Ash Water Titration: Introduce acid-base titrations in a very unique way. This green chemistry version of a strong acid-strong base titration uses wood ash, a renewable source of base, instead of NaOH. Concepts: acids and bases, titration, catalysis, sustainability and indicators.
    • Road Deicers: Learn a quick way to assess the relative toxicities of chemicals commonly found in road deicers. This lab has students examine the effects of aqueous solutions of sodium chloride, magnesium chloride and calcium chloride. Concepts: serial dilution, assays, ecotoxicity, environmental science.
    • Making a Household Surface Cleaner: Convert a polylactic acid plastic cup into a household surface cleaner with chemistry while learning about Green Chemistry and polymer chemistry! Concepts: polymers, renewable resources, acids and bases and hydrolysis. 

    More information at Flinn Scientific: https://goo.gl/qct3vw

    Teacher observations of green chemistry in their classrooms

    “The students thought it was so cool that they could use blackberries to make a solar cell. I know that they will look for things in their lives to reduce impact on Earth’s environment.” Connie, Middle School Teacher.

    “The students were impressed with the ability to rearrange the atoms into something completely different. It showed a practical application of chemistry, and how the knowledge of chemistry might lead to new technologies.” Laurie, High School Chemistry Teacher.

    About Beyond Benign

    Co-founded by Dr. John Warner and Dr. Amy Cannon in 2007 as a 501c3 nonprofit, Beyond Benign develops and disseminates educational content that teaches green chemistry innovation and empower educators and students to learn how chemistry is central to innovating sustainable solutions. Beyond Benign’s programs support an educational continuum from K-12 to higher education to industry. The organization works directly with educators and a network of strategic partners focused on science education, sustainability, innovation and initiatives supporting human and environmental health.

    About Flinn Scientific

    Flinn Scientific supports science educators in opening young minds to the challenges and joys of scientific discovery. Flinn understands that science is a primary source of America’s unparalleled productivity, quality of life, and technological leadership. Through their unsurpassed customer service, they provide the science community with the very best education supplies, safety information, instructional materials and programs to facilitate their vital work. Flinn’s respect for and loyalty to the science community is central to everything they do and their relationship with them is always their first priority. 

     

     

    Implementing the Claim, Evidence, Reasoning Framework in the Chemistry Classroom

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    Claims, Evidence & Reasoning example

    As a science teacher, few things beat a high-quality scientific explanation from a student. However, the frequency of such explanations often seems far and few between. Yet year after year, I grade hundreds of lab reports and short answer questions only to consistently feel like I’m sitting at a slot machine experiencing a bunch of “near misses”, several “not-even-close calls”, and just a few “jackpots”. So how can we, as teachers, develop our students’ ability to consistently create better scientific explanations and arguments?

    For me, the first step toward teaching my students how to critically think about how they structured an argument or explanation was to implement the Claim, Evidence, Reasoning (CER) framework. While the premise behind CER isn’t anything new to the way science teachers already think, it provides an entirely different approach toward how students connect their experiences and previously learned content into something that is much more reflective of being scientifically literate. Though you may have already guessed from the name itself, applying the CER framework to an explanation or argument goes something like this1.

    Claim: A statement of a student’s understanding about a phenomenon or about the results of an investigation

    • A one-sentence answer to the question you investigated
    • It answers, what can you conclude?
    • It should not start with yes or no.
    • It should describe the relationship between dependent and independent variables.

    Evidence: Scientific data used to support the claim

    Evidence must be:

    • Sufficient—Use enough evidence to support the claim.
    • Appropriate—Use data that support your claim. Leave out information that doesn’t support the claim.
    • Qualitative, Quantitative, or a combination of both.

    Reasoning: Ties together the claim and the evidence

    • Shows how or why the data count as evidence to support the claim.
    • Provides the justification for why this evidence is important to this claim.
    • Includes one or more scientific principles that are important to the claim and evidence.

    A more thorough summary of the CER framework can be seen below in a nice 7-minute video created by Paul Anderson of Bozeman Science2.

    You can also read more about the CER framework from Activate Learning. I encourage you to download their CER poster for your classroom.


    REFLECTING ON MY OWN EXPERIENCE WITH USING CLAIMS, EVIDENCE AND REASONING

    Though you will experience your own journey upon implementation, I wanted to offer a few of my own thoughts and experiences that answer some of the primary questions I had before starting to interweave this framework into my curriculum.

    #1 - How do I introduce this to my students?

    By the time students reach us in their late high school or early college career, they would have already had 2-3 years of science classes. While you can be reasonably certain that they had been exposed to writing conclusions, or providing short answer explanations to conceptual questions, it’s likely that they had never been explicitly taught the merits of a quality explanation or given intentional practice to work on this skill. Because of this, I recommend introducing the CER framework in a non-scientific context so that students can more easily pick up on the anatomy of a good explanation with the intention that they will eventually be able to transfer these new thinking patterns to a scientific context later. Though there are hundreds of fun ways to do this, here is one way I have introduced CER the past couple years. Watch the video and take a look!

    I discovered this commercial while reading Trevor Register's blog post about his CER implementation experience. The little girl in the video believes her dad is an alien and provides multiple pieces of evidence as to why she believes this to be true. Not only is it cute and humorous, but everything she mentions inadvertently provides an awesome opportunity for students to do three things that are fundamentally important when introducing CER.

    • Examine each piece of evidence mentioned and determine if it supports the claim or not.
    • Upon examining the evidence, students have an opportunity to critically think about why each piece of evidence justifies her claim. In other words, why would “speaking a weird language” or “drinking green stuff” justify the claim that her dad is an alien? That part is pretty fun to talk about with students.
    • It gives them an opportunity to hear an inaccurate explanation that sounds like an accurate one. No matter how adorable the little girl is, we can safely agree that her lack of experience on this Earth has allowed her to make connections between her evidence and claim that simply are not true. To the girl, her argument sounds completely valid. But to the rest of us, we are able to quickly discount each piece of evidence provided simply because we have more experience and knowledge than the little girl does. Though students may laugh for the moment and reminisce about how fun it was to be little, the humorous thing is that many of them will actually end up doing the same thing this little girls did early on with their evidence for chemistry explanations—to which I am quickly able to discount!

    I will typically ask for students to construct their own CER first and then get into small groups to discuss the merits and any potential holes in each argument. It takes a bit more facilitation by me to get them to realize the point of inaccurate reasoning beyond the simple example of the little girl but students quickly pick up on the message I am trying to get across. The process is fun and, most importantly, meaningful. It truly does provide an easy way to introduce a more complex way of thinking about how we explain things in science.

    As students start to gradually improve their CER skills, teachers should work in relatively easy science examples like Francesco Redi’s famous investigation of spontaneous generation. My own use of this example can be found in the supporting information at the bottom of this post.


    #2 - Is this only for lab reports or can I use this for homework, quizzes, tests, presentations, etc. too?

    The answer to this can be whatever you want it to be. During my 1st year of implementation, I only used CER in the lab setting. I regret that decision because the nature of our content provides opportunities for students to practice and reflect on their scientific explanations pretty much daily. Adhering only to the lab setting may allow students to think that somehow their explanations of findings in the lab have a fundamentally different structure than the answers I ask them to provide on an assessment. This year, for the first time, I have started to incorporate CER into my quizzes, tests, labs, and homework.

    #3 - What are some chemistry examples of student work?

    Here are a few that I grabbed from a variety of activities we have done throughout the year.


    Example A - Identifying unknown ions from data:

    Several more good/bad student examples from this lab can be found in the supporting information at the bottom of this post.


    Example B - Error analysis in stoichiometry precipitate lab:

    Claim: One source of error that affected our percent yield was our filter not being closed enough when in the funnel.

    Evidence: The water coming out of the filter was not 100% clear and had some cloudiness to it.

    Reasoning: If the water was not clear that meant that some of the precipitate was flowing out in the water and went down the drain and didn't make it into the final mass of the solid Pb(OH)2.


    Example C - Determining the mathematical relationship between molarity, moles of solvent, and volume of solution:



    Example D - Investigating the effect of excercise on CO2 production in the body:


    Example E - An example of "inappropriate reasoning" from a stoichiometry lab:


    #4 - How do I grade CER assignments?

    The most efficient and accurate method I can suggest is to create a uniform rubric that will be used for every CER explanation. Though the explanations will differ based on content, the general structure to them will always be the same. You can find CER grading rubrics on the internet but it is not difficult to create your own once you understand what each piece of the framework looks like when done properly. Here is a relatively simple one that I have been using throughout the year.

     

    #5 - How do I convince my colleagues to try this with me?

    Though we may have disagreements on classroom policies, grading, or even educational philosophy, you can be fairly confident that all of your science colleagues will at least agree on their answers to the following question:

    Do you want your students to become better at constructing evidence-based explanations and arguments?

    If the answer to this is yes and you have a potential framework to offer that can accomplish such a task, aligns with what the NGSS standards advocate for, and already has enough of a foundation in the scientific education community to be taken seriously, then it will leave them with little room to comfortably say no. If time is the immediate obstacle, then you will find a way to rethink how you spend time currently and make the appropriate modifications.

     

    I am proud and thankful to be part of a chemistry department that was willing to accept the integration of CER. Doing so has allowed us to share, compare, and reflect on student work in ways that we rarely would have ever done in the past. If you decide to do this as a team of teachers, I strongly encourage you to make sure that everyone is on the same page about what CER is, what it looks like, and even how you all plan to grade it.

     

    Honestly, it took us months before we realized that maybe it would be a good idea to do something like individually grade a student’s CER example to compare grading and discuss our reasoning. Doing a simple exercise like this quickly made us quickly realize that we were not all on the same page about what we defined as “high quality”. This exercise helped us to constructively argue and become more aligned with each other.

     

    Even if you are just the lone wolf using CER, at least you can be confident that you are intentionally trying to make a difference in building a skill that will help students well beyond their academic career even if it is outside of the scientific context.

    #6 - How much time does this take to produce meaningful results?

    I can honestly say that consistently and effectively implementing this was (and still is) a process that simply takes time. It is not something subtle like introducing daily warm up questions, exit slips, or new ways of giving formative assessments. It really is a classroom cultural shift with respect to how students interact with their thinking and, because of that, it takes time. The time it takes to produce the results you want largely depends upon your commitment to providing frequent exposure, giving feedback, offering “re-dos”, and consistently communicating the characteristics of a quality scientific explanation.



    Final Thoughts

    Though I have only been using the CER framework for the past 2 years, it has caused me to completely rethink the expectations I have for lab conclusions, short answer explanations, and argument building. This approach has adhered to our classroom culture enough that it's even gotten to the point where my own students find ways to vindictively use the framework against me when trying make the case for the Dallas Cowboys being the best team in the NFL or whether they should been given a test next Friday! As far as I'm concerned, the more scenarios I can get them to say "what evidence do you have for this?" then I am helping build a skill that will act as a useful filter for the truth in a world of constant information exposure. I am glad I was introduced to CER and I continue to look for better ways to implement it. If this sounds like something you are interested in, I recommend just trying it out for a while and see the kind of results you get from your students. I have found that more of my students are now writing high-quality scientific explanations. That is an area I have wanted to see improvement in since I began teaching!  Feel free to share any experiences you have had with CER or anything related to evidence-based explanations.


    References:

    1"Claim Evidence Reasoning CER | Activate Learning — Activate ...."http://www.activatelearning.com/claim-evidence-reasoning/. Accessed 10 Feb. 2017.

    2"CER - Claim Evidence Reasoning - YouTube." 9 Jan. 2017, https://www.youtube.com/watch?v=5KKsLuRPsvU. Accessed 10 Feb. 2017.

    3"Audi "My Dad's a Space Alien" - YouTube." 25 Sep. 2012, https://www.youtube.com/watch?v=sVRAtQ7XjkM. Accessed 10 Feb. 2017.

     

     

    Especially JCE: February 2017

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    “The common image of chemistry is in fact a rather wretched one, full of hazards, risks, and pollution. The word ‘chemicals’ has become synonymous with ‘dangerous substances’ in the popular culture. ‘Unfair,’ we chemists cry, ‘and so uninformed.’ But what is being done to improve the public’s perception of chemistry?”

    Does the above Journal of Chemical Education (JCE) excerpt match your view of the general public’s perception of chemistry in 2017? If so, you may be interested to learn that these comments appeared over twenty years ago, on the pages of the September 1996 issue. Its author, Richard N. Zare, then the newly appointed Chair of the governing body of the National Science Foundation, linked his question with the results of a survey of science museums. The survey showed a distinct lack of chemistry in science museums—a missed opportunity to impact this negative perception.

    Zare recognized that the pages of JCE are a good place to mine for ideas about exhibits and encouraged readers to share their successful experiences of working with science museums. Articles specifically related to this topic have cropped up here and there in the intervening twenty years, and the February 2017 issue of JCE offers another that could serve the high school teacher as well as science museum exhibit planners: Bringing Organic Chemistry to the Public: Structure and Scent in a Science Museum (available to JCE subscribers).

    The authors describe an exhibit with several purposes: “to make organic molecules relatable to the general public,” “to make chemicals less intimidating,” and to communicate that “scents are chemicals, and molecular structure determines biological activity.” Visitors smell various “Scent Bottles” with a goal of identifying the scent. Each bottle has an associated molecular model that shows a related scent compound. The exhibit also provides molecular model kit pieces and handouts for hands-on building of scent molecules. Part of the exhibit shows pairs of molecules that are related to each other structurally. I was amused at one handout’s instruction to “Turn vomit into pineapple!” I can easily picture it appealing to some students, but also appreciate that it shows just how close the two structures are to one another. The molecular model materials and instructions can be reused from year to year.

    Figure 4 – Reprinted with permission from Bringing Organic Chemistry to the Public: Structure and Scent in a Science Museum M. Kevin Brown, Laura C. Brown, Karen Jepson-Innes, Michael Lindeau, and Jeremy Stone. Journal of Chemical Education, 94 (2), 251-255. Copyright 2017 American Chemical Society.

    For those who wish to create the Scent Bottles, I asked the corresponding authors for advice on locating and purchasing the various scents. Many of the chemicals they used were on hand in their department’s stockroom, or they ordered them from chemical companies. Other options were suggested:

    Grocery store (these are items where the scent is basically the pure compound): microwave popcorn (diacetyl), almond extract (benzaldehyde), vanilla extract (vanillin), cinnamon extract (cinnamaldehyde), vinegar (acetic acid), menthol (menthol, not included in the paper), and spearmint extract (R-carvone; S-carvone is the characteristic smell of caraway - I see that extract is also available).

    Internet: Butyric acid (vomit) is apparently available (quick google search), but the others might be more difficult to obtain. Pineapple and banana extracts are available, but I’m not sure what the exact compositions are. Amyl acetate (also banana) is available, and my guess is that they’d be able to find most of the fruit esters as well.

    Other classrooms: Geosmin is expensive to buy, but if there is a biology teacher nearby who knows how to grow streptomyces bacteria, the characteristic smell that will emanate from the plates is geosmin. (L. C. Brown, personal communication, February 13, 2017)

    How might chemical educators use the ideas from the article?

    • Turn the exhibit into a hands-on classroom activity for your students.

    One possibility for adapting the “Scent Bottles” would be to use Jelly Belly brand jelly bean flavors (including the more disgusting ones offered with Bertie Bott’s Every Flavour Beans, such as dirt and vomit) for guessing, since the sense of smell plays a major role in how we perceive flavor. Or, the exhibit’s molecule building activities could be used as a first, directed attempt at general molecular model building, or as an introduction to organic molecules.

    • Use the exhibit as a hands-on activity for community outreach, such as at a science night event, a school open house, or during outreach to elementary schools.
    • Collaborate with a local science or children’s museum to offer such an exhibit, either as described or on a smaller scale.

    More from the February 2017 Issue

    Don’t miss Mary Saecker’s JCE 94.02 February 2017 Issue Highlights for further content from this month’s issue of the Journal. Lots of article titles sparked my interest this month.

    Have something to say about a current or past article from JCE? We want to hear! Start by submitting a contribution form, explaining you’d like to contribute to the Especially JCE column. Then, put your thoughts together in a blog post. Questions? Contact us using the ChemEd X contact form.

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    JCE 94.02 February 2017 Issue Highlights

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    Journal of Chemical Education February 2017 Cover

    Fostering Creativity in Chemistry

    The February 2017 issue of the Journal of Chemical Education is now available online to subscribers. Topics featured in this issue include: surface chemistry; chemical identity thinking; conceptual understanding; communicating science to the general public; activities and labs linking chemistry and art; history and chemistry; early access to research; technology as instructional support; synthesis laboratories; from the archives: bottle chemistry.

    Cover: Surface Chemistry

    In Demonstrating the Effect of Surfactant on Water Retention of Waxy Leaf Surfaces, Yu-Chun Chiu, Matthew A. Jenks, Michelle Richards-Babb, Betsy B. Ratcliff, John A. Juvik, and Kang-Mo Ku discuss an inexpensive and engaging laboratory-based activity to help students learn about the scientific method as well as the role of plant epicuticular waxes and surfactant function on waxy plant leaves. This lab can also be used to further students’ understanding of more advanced chemical concepts (such as intermolecular forces, hydrophobicity, surface tension, and the dual polarity of surfactants) and as a practical example of issues faced by the agricultural industry.

    Surface science is also discussed and demonstrated in these articles:

    Aqua-Art: A Demonstration of Hydrophilic and Hydrophobic Surfaces Fabricated by Plasma Enhanced Chemical Vapor Deposition ~ Shauna P. Flynn, Milena McKenna, Ruairi Monaghan, Susan M. Kelleher, Stephen Daniels, and Aoife MacCormac

    Self-Motion of Sodium Benzoate Flakes on a Water Surface: A Demonstration ~ Katherine V. Darvesh and Earl Martin

    Editorial

    In this month's editorial, Editor-in-Chief Norbert J. Pienta scales The Slippery Slope of Student Evaluations.

    Chemical Identity Thinking

    Capturing Chemical Identity Thinking (Chemical Education Research) ~ Courtney Ngai and Hannah Sevian

    Conceptual Understanding

    Using Interlocking Toy Building Blocks To Assess Conceptual Understanding In Chemistry ~ Michael J. Geyer

    Using Students’ Conceptions of Air To Evaluate a Guided-Inquiry Activity Classifying Matter Using Particulate Models ~ D. Amanda Vilardo, Ann H. MacKenzie, and Ellen J. Yezierski

    Communicating Science to the General Public

    Exploration of a Method To Assess Children’s Understandings of a Phenomenon after Viewing a Demonstration Show (Chemical Education Research) ~ Brittland K. DeKorver, Mark Choiand, and Marcy Towns

    A Reverse Science Fair that Connects High School Students with University Researchers ~ Brian Mernoff, Amanda R. Aldous, Natalie A. Wasio, Joshua A. Kritzer, E. Charles H. Sykes, and Karen O’Hagan

    Bringing Organic Chemistry to the Public: Structure and Scent in a Science Museum ~ M. Kevin Brown, Laura C. Brown, Karen Jepson-Innes, Michael Lindeau, and Jeremy Stone

    Activities and Labs Linking Chemistry and Art

    The Chemistry of Photography: Still a Terrific Laboratory Course for Nonscience Majors ~Simeen Sattar

    Colorful and Creative Chemistry: Making Simple Sustainable Paints with Natural Pigments and Binders ~ Jillian L. Blatti

    An Advanced Spectroscopy Lab That Integrates Art, Commerce, and Science as Students Determine the Electronic Structure of the Common Pigment Carminic Acid ~ Suqing Liu, Asami Odate, Isabella Buscarino, Jacqueline Chou, Kathleen Frommer, Margeaux Miller, Alison Scorese, Marisa C. Buzzeo, and Rachel Narehood Austin

    Pigment Synthesis for the Exploration of Binding Media Using a Lead-Free Alternative to Chrome Yellow ~ Anne C. Gaquere-Parker, Patricia S. Hill, Michael P. Haaf, Cass D. Parker, N. Allie Doles, Amanda K. Yi, and Todd A. Kaminski

    History and Chemistry

    Mapping the Teaching of History of Chemistry in Europe (Commentary)~ Ignacio Suay-Matallana ad and José Ramón Bertomeu Sánchez

    Periodic Reactions: The Early Works of William C. Bray and Alfred J. Lotka ~ Rinaldo Cervellati and Emanuela Greco

    Early Access to Research

    Activities in an S-STEM Program To Catalyze Early Entry into Research ~Kate J. Graham, Edward J. McIntee, Annette F. Raigoza, M. Abul Fazal, and Henry V. Jakubowski (This article is available to non-subscribers as part of ACS’s AuthorChoice program.)

    Competence-Based, Research-Related Lab Courses for Materials Modeling: The Case of Organic Photovoltaics ~ Karl Sebastian Schellhammer and Gianaurelio Cuniberti

    Technology as Instructional Support

    In-Class Versus At-Home Quizzes: Which is Better? A Flipped Learning Study in a Two-Site Synchronously Broadcast Organic Chemistry Course ~ Michael A. Christiansen, Alyssia M. Lambert, Louis S. Nadelson, Kami M. Dupree, Trish A. Kingsford

    Qualitative and Quantitative Evaluation of Three Types of Student-Generated Videos as Instructional Support in Organic Chemistry Laboratories ~ Melinda C. Box, Cathi L. Dunnagan, Lauren A. S. Hirsh, Clinton R. Cherry, Kayla A. Christianson, Radiance J. Gibson, Michael I. Wolfe, and Maria T. Gallardo-Williams

    Stereogame: An Interactive Computer Game That Engages Students in Reviewing Stereochemistry Concepts ~ José Nunes da Silva Júnior, Mary Anne Sousa Lima, João Victor Xerez Moreira, Francisco Serra Oliveira Alexandre, Diego Macedo de Almeida, Maria da Conceição Ferreira de Oliveira, and Antonio José Melo Leite Junior

    Synthesis Laboratories

    Teaching Experiment To Elucidate a Cation−π Effect in an Alkyne Cycloaddition Reaction and Illustrate Hypothesis-Driven Design of Experiments ~ Elijah J. St.Germain, Andrew S. Horowitz, Dominic Rucco, Evonne M. Rezler, and Salvatore D. Lepore

    Thiourea in the Construction of C–S Bonds as Part of an Undergraduate Organic Chemistry Laboratory Course ~ Guo-ping Lu, Fei Chen, and Chun Cai

    Preparing 4-Ethoxyphenylurea Using Microwave Irradiation: Introducing Students to the Importance of Artificial Sweeteners and Microwave-Assisted Organic Synthesis (MAOS) ~ Spence C. PilcherJoshua Coats

    From the Archives: Bottle Chemistry

    This issue includes a low-cost method by Dawid Siodłak for Building Large Molecular Models with Plastic Screw-On Bottle Caps and Sturdy Connectors. Articles in past issues of JCE have used soda bottles in a variety of innovate ways to teach chemistry:

    Out of the Blue (JCE Classroom Activity on the Blue Bottle) ~ Mark E. Noble

    Improvements to the Whoosh Bottle Rocket Car Demonstration ~ Dean J. Campbell, Felicia A. Staiger, and Chaitanya N. Jujjavarapu

    The Dynamic Density Bottle: A Make-and-Take, Guided Inquiry Activity on Density ~ Thomas S. Kuntzleman

    Kinetic Explorations of the Candy–Cola Soda Geyser ~ Trevor P. T. Sims and Thomas S. Kuntzleman

    Exploring the Gas Chemistry of Old Submarine Technologies Using Plastic Bottles as Reaction Vessels and Models ~ Ryo Horikoshi, Fumitaka Takeiri, Yoji Kobayashi, and Hiroshi Kageyama

    Sink or Swim: The Cartesian Diver (JCE Classroom Activity) ~ K. David Pinkerton

    A New Quantitative Pressure-Volume Experiment Based on the "Cartesian Diver" ~Judith U. S. Thompson and Kenneth A. Goldsby

    More Chemistry in a Soda Bottle: A Conservation of Mass Activity ~ William O. Bare, Kenneth A. Goldsby, Daniel Q. Duffy, and Stephanie A. Shaw

    Visualizing Gas Adsorption on Porous Solids: Four Simple, Effective Demonstrations ~ Ocean Cheung

    Simple Soda Bottle Solubility and Equilibria ~ Cheryl A. Snyder and Dudley C. Snyder

    A Million Reasons to Explore JCE

    With over 1,000,000 downloads of content each year, you will always sure to find something useful—including the articles mentioned above, and many more, in the Journal of Chemical Education. Articles that are edited and published online ahead of print (ASAP—As Soon As Publishable) are also available.

    Do you have something to share? Write it up for the Journal! For some advice on becoming an author, read Erica Jacobsen’s Commentary. In addition, numerous author resources are available on JCE’s ACS Web site, including recently updated: Author Guidelines, Document Templates, and Reference Guidelines.

     

     

    Julia Winter - Teacher & CEO

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    Winter & Cullen at ACS SanDiego

    Julia Winter has been an energetic and inventive teacher for more than 20 years at Detroit Country Day in Beverly Hills, Michigan. She has always challenged herself to try new things and stay abreast of recent advances in teaching of chemistry. The past few years have been especially exciting. She has worked with a mobile game developer to tranform a whiteboard game into a mobile app that helps students to learn organic chemistry concepts. In January 2016, Julia made the emotional decision to take a leave of absence from teaching. She can now devote all of her energy to pursuing grants and developing even more games as CEO of Alchemie. In March of 2016, I was priviliged to interview Julia. I invite you to view the video and hear her energy and passion for yourself. 

    Read the Journal of Chemical Education article related to this interview, Teacher CEO

    Read an Tech Report Julia co-authored for the Journal of Chemical Education, Chairs!: A Mobile Game for Organic Chemistry Students To Learn the Ring Flip of Cyclohexane.

    Read Julia's guest ChemEd X blog post, A Thing for Chairs

    Visit the Alchemie/Chairs! website. 

     

     

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